Head to Head
| UEFA Europa League | 2022/02/24 20:00 | Napoli v Barcelona | L | 2-4 |
| UEFA Europa League | 2022/02/17 17:45 | Barcelona v Napoli | D | 1-1 |
| UEFA Champions League | 2020/08/08 19:00 | Barcelona v Napoli | L | 3-1 |
| UEFA Champions League | 2020/02/25 20:00 | Napoli v Barcelona | D | 1-1 |
| Club Friendly List | 2019/08/10 21:00 | Napoli v Barcelona | L | 0-4 |
| Club Friendly List | 2019/08/07 23:30 | Barcelona v Napoli | L | 2-1 |
| World Club Friendlies | 2014/08/06 18:00 | Barcelona v Napoli | W | 0-1 |